合成立方氧化锆的新品种——“重锆”合成材料
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P578.4;P575

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国家自然科学基金项目(41772033)


A new variety of synthetic cubic zirconia: Characterization of the novel “Heavy-zircon” material
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    摘要:

    2024年,广西梧州人工宝石市场出现了一种被称为“重锆”的人工合成立方氧化锆新品种。这种新的合成材料目前尚无详细报道,其成分及结构特征亦不为业界所知。本文利用电子探针、X射线衍射、红外光谱、拉曼光谱等方法对收集到的重锆样品进行了系统的宝石学和矿物学特征研究。结果表明,重锆的相对密度约为7.40,主要化学成分为Yb2O3和ZrO2,Yb2O3含量约51.08%~53.06%,可含少量的Y2O3。相对原子质量更大的重稀土元素Yb的掺入导致重锆的密度偏高。重锆为等轴晶系,萤石型结构,空间群Fm3m,晶胞参数a=5.134 8(18)Å,晶胞体积为135.39(8) Å3,依据本次测试数据计算的化学式为Zr0.57Yb0.40Y0.03O1.780.22或Zr0.59Yb0.41O1.790.21(□: 氧空位)。本文建议重锆的宝石学名称为“合成富镱立方氧化锆”。

    Abstract:

    In 2024, a previously undocumented synthetic cubic zirconia product, traded as "heavy-zircon", emerged in the Wuzhou gem market (Guangxi, China). To address the lack of peer-reviewed data on its composition and identity, we performed a comprehensive mineralogical and gemological study using electron-probe microanalysis (EPMA), X-ray diffraction (XRD), fourier-transform infrared (FTIR), and micro-Raman spectroscopy. The material has a high relative density of approximately 7.40 and is primarily composed of Yb2O3 (51.08%~53.06%) and ZrO2, with minor Y2O3. Its elevated density results from the incorporation of ytterbium (Yb), a heavy rare earth element. Single-crystal XRD confirms an isometric fluorite-type structure (space group Fm3m) with a lattice parameter a=5.134 8(18) Å and a unit-cell volume V=135.39(8) Å3. The calculated chemical formulas are Zr0.57Yb0.40Y0.03O1.780.22 or Zr0.59Yb0.41O1.790.21 (□ denotes oxygen vacancy). These results identify heavy-zircon as a high-density, ytterbium-rich variant of yttria-stabilized cubic zirconia. In accordance with gemological nomenclature, we propose "synthetic ytterbium-rich cubic zirconia" as its formal species name.

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范桂珍,王长秋,沈才卿,等, 2025. 合成立方氧化锆的新品种——“重锆”合成材料[J]. 岩石矿物学杂志, 44(6):1464~1470.
FAN Gui-zhen, WANG Chang-qiu, SHEN Cai-qing, et al, 2025. A new variety of synthetic cubic zirconia: Characterization of the novel “Heavy-zircon” material[J]. Acta Petrologica et Mineralogica, 44(6): 1464~1470.

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  • 收稿日期:2025-06-01
  • 最后修改日期:2025-09-28
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  • 在线发布日期: 2025-11-21
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