显微激光拉曼光谱锆石定年方法及其应用
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P597+.3

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国家自然科学基金项目(41972064)


Zircon dating by laser Raman spectroscopy and its application
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    摘要:

    锆石是岩浆岩、沉积岩和变质岩中的常见副矿物,由于其具有高Th、U含量的特点,已成为地质年代学研究的理想矿物之一。显微激光拉曼光谱锆石定年方法的原理是锆石中U、Th原子自发的α衰变而引起其自身晶格的辐射损伤,锆石晶格破坏的积累和时间呈正相关关系,并且与锆石拉曼光谱半高宽Γ具有相关性。利用锆石显微激光拉曼光谱仪测量锆石特征峰的半高宽可以计算出锆石的辐射损伤累积,进而计算得到锆石发生辐射损伤所累计的时间。锆石辐射损伤定年方法具有空间分辨率高、样品制备和测试方法简单等优势。但是此方法也受控于诸多影响因素,例如锆石自身结构的不均一性、锆石发生热退火作用的速率、锆石重结晶作用及辐射损伤饱和度等对定年结果均具有影响。显微激光拉曼光谱锆石定年方法的建立将有助于判定碎屑锆石物源区、揭示岩体热演化史以及识别继承锆石经历的后期构造热事件等研究。本文从显微激光拉曼光谱锆石定年方法的基本原理、计算过程及年龄影响因素等方面对该方法进行了介绍,并通过对松多高压变质带中变泥质岩中锆石的年代学研究,结合前人的应用实例,对该方法的应用前景进行了展望,为锆石年代学研究提供新的技术手段。

    Abstract:

    Zircon is a common accessory mineral in magmatic rocks, sedimentary rocks and metamorphic rocks. Due to its characteristics of high Th and U, zircon has become one of the ideal minerals in the study of geochronology. The principle of the microscopic laser Raman spectroscopy zircon dating method is that the spontaneous α decay of U and Th atoms in zircon causes damage to their own crystal lattice.The accumulation of lattice damage in zircon is positively correlated with the time, and also is correlated with the full width at half maximum Γ of zircon Raman spectrum. The cumulative radiation damage of zircon can be calculated by measuring the full width at half maximum of zircon characteristic peaks with zircon micro laser Raman spectrometer. Thus, the cumulative time of radiation damage can be calculated. Zircon radiation damage dating has the advantages of the high spatial resolution, simple sample preparation and testing methods. However, this method is also subject to various influencing factors, such as the heterogeneity of zircon structure, the rate of thermal annealing, the recrystallization of zircon and radiation damage saturation, all of which would affect the final dating results. The establishment of micro-laser Raman spectroscopy zircon dating method could help to determine the source area of detrital zircon, to reveal the thermal evolution history of rock mass and to identify the later metamorphic thermal events experienced by the inherited zircon. This paper introduces the basic principle, calculation process and age influencing factors of micro-laser Raman spectroscopy zircon dating method. This method is applied for the study of zircon chronology in the metapelites of the Sumdo high pressure metamorphic belt. It provides a new technical method for the zircon chronology.

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赵晓轩,张聪,刘晓瑜,等, 2024. 显微激光拉曼光谱锆石定年方法及其应用[J]. 岩石矿物学杂志, 43(2):450~468.
ZHAO Xiao-xuan, ZHANG Cong, LIU Xiao-yu, et al, 2024. Zircon dating by laser Raman spectroscopy and its application[J]. Acta Petrologica et Mineralogica, 43(2): 450~468.

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  • 收稿日期:2023-11-29
  • 最后修改日期:2024-01-17
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  • 在线发布日期: 2024-03-16
  • 出版日期: 2024-03-25
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