江西赣南风化淋滤型稀土矿床中的粘土矿物研究
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国家自然科学基金青年基金项目(41302030);中国地质大调查项目(12120113015100);科技支撑项目(2011BAB04B07);深部探测与实验研究项目(201311165)


The study of clay minerals from weathered crust rare earth ores in southern Jiangxi Province
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    摘要:

    对江西赣南6个地区风化淋滤型稀土矿中全风化层的粘土矿物进行了研究,为进一步了解粘土矿物对该类型稀土矿中稀土元素分异的影响奠定了基础。X射线衍射自然定向片、甲酰胺片、饱和乙二醇片和加热片、红外光谱及扫描电镜观察结果表明该区粘土矿物以片状高岭石和针管状7Å埃洛石为主,其中坳背塘、长坑屋、上堡、杨村样品主体为高岭石,足洞样品中发育大量埃洛石,而石排样品中高岭石与埃洛石比例相当。电感耦合等离子体质谱分析表明稀土元素在粘土矿物中大量富集,其稀土元素配分不仅受到原岩的影响,而且受到粘土矿物本身性质的影响。Ce元素在足洞和石排样品的粘土矿物中表现出正异常,而在其他样品粘土矿物中表现为负异常,可能与其中发育的埃洛石密切相关。Ce元素可能以方铈矿胶膜的形式包裹在针状埃洛石中,和/或以离子形式被选择性吸附于埃洛石表面。

    Abstract:

    The clay minerals from the weathered crust rare earth ores of six areas in Jiangxi Province were studied for better understanding the effects of clay minerals on the rare earth fraction. The powder X-ray diffraction(XRD), infrared spectroscopy(IR) and scanning electron microscopy(SEM) results show that platy kaolinite and tubular 7Å halloysite are predominant constitutions in clays. Kaolinite and 7Å halloysite are dominant in ABT, CKW, SB, YC samples and ZD sample respectively, and both of them are abundant in SP sample. Inductively coupled plasma mass spectrometry(ICP-MS) analysis indicates that rare earth elements tend to be concentrated in clay minerals. The rare earth distribution patterns are influenced by both the original rock and the properties of clay minerals. A positive Ce-anomaly has been found in ZD and SP samples compared with a negative Ce-anomaly in other samples, which might be correlated to the well developed halloysite in these two samples. It is possible for Ce to be present as cerianite which is coating halloysite needles and/or be selectively absorbed by hallyosite which has higher specific surface area and cation exchange capacity than kaolinite.

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范晨子,张誉,陈郑辉,等, 2015. 江西赣南风化淋滤型稀土矿床中的粘土矿物研究[J]. 岩石矿物学杂志, 34(6):803~810.
FAN Chen-zi, ZHANG Yu, CHEN Zheng-hui, et al, 2015. The study of clay minerals from weathered crust rare earth ores in southern Jiangxi Province[J]. Acta Petrologica et Mineralogica, 34(6): 803~810.

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  • 收稿日期:2015-04-13
  • 最后修改日期:2015-10-12
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  • 在线发布日期: 2015-11-24
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