埃塞俄比亚染色欧泊的研究
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A study of dyed opals from Ethiopia
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    摘要:

    目前,埃塞俄比亚染色欧泊在我国市场上屡见不鲜.本文采用常规宝石学测试手段、光谱分析、吸水实验、浸泡褪色实验和浸泡染色实验等方法对市场上常见的3种颜色的埃塞俄比亚染色欧泊进行了研究.结果表明,这些埃塞俄比亚染色欧泊主要通过浸泡于不同颜色的化学颜料溶液中上色,浸泡过程中往往添加含有羧酸根离子的表面活性剂或颜料超分散剂(如邻苯二甲酸酯),以使颜料颗粒分布更加均匀,这主要是由于埃塞俄比亚欧泊的孔隙度相对较大,对染料的吸附性相对较强.这些埃塞俄比亚染色欧泊的主要特征如下: ① 亚透明至微透明,染橙色和染蓝色样品具有弱至强的变彩,染黑色样品体色以灰蓝色或黄灰色为主,具有强烈的红色、黄色、绿色和蓝色变彩;透射光下照射,染黑色欧泊具有强至弱的红色调以及明显的染剂不均匀富集现象. ② 埃塞俄比亚染色欧泊和其天然欧泊一样吸水性强,吸水后密度、质量均有所增加,透明度增强,变彩可能会有所增强,也可能会有所减弱,染色欧泊密度范围为1.63~1.86 g/cm3,折射率在1.40(点测)左右,与天然欧泊一致,均低于澳大利亚和墨西哥的欧泊. ③ 在高倍显微镜下观察,染色样品颜色分布不均,内部常见色点、色斑、色块或色团分布,在表面部位染剂富集现象更为明显,常见染剂沿着边缘、刮痕或凹坑处富集. ④ 染色欧泊浸泡在不同的溶剂中会使溶剂变色. ⑤ 拉曼光谱表明,染色欧泊出现了很强的荧光背景及弱的热效应峰3 362 cm-1,拉曼散射峰很弱. ⑥ 紫外可见光分光光谱表明,埃塞俄比亚染色欧泊与天然欧泊的吸收光谱不同.

    Abstract:

    Recently, dyed opals from Ethiopia are often seen in the market. The Ethiopian dyed opals with three kinds of common colors were studied in this paper using ordinary gemological testing methods, spectrum analysis and other methods such as absorbent experiment, soaking fading experiments and soaking dye experiments. The results show that these Ethiopian dyed opals are mainly dyed by soaking the opals in chemical pigments solutions of different colors in consideration of their relatively bigger porosity and stronger dye absorption. The surfactant containing carboxylate ions or hyperdispersant (e.g. phthalate) is often used to disperse pigments granules more evenly. The identification characteristics of Ethiopian dyed opals are as follows: ① Semitransparent to semitranslucent, dyed orange and blue samples have strong to weak play of color, whereas dyed black samples are mostly grayish blue or yellowish gray in color with strong red, yellow, green, and blue play of color, as well as strong to weak red tone and uneven dye concentration phenomenon under transmitted light. ② The absorbent of dyedopals from Ethiopia is as strong as that of the natural ones; once they absorb water, the density and weight both increase obviously, the transparence becomes stronger, and the play of color may be enhanced or weakened; the densities of dyed opals from Ethiopia vary in the range of 1.63~1.86 g/cm3, and the refractive index is 1.40, which are consistent with the data of natural ones from Ethiopia but are lower than corresponding data of opals from Australia and Mexico. ③ Observation under high-power microscope shows that the colors of the dyed opal samples are unevenly distributed: there are dye dots, dye spots, dye lumps in the inner part, more obvious dye concentration along edges, scratches and pits at the surface. ④ The solvents will change color when dyed opals are soaked in them. ⑤Roman spectrum shows that dyed opals exhibit strong fluorescent background, weak 3 362 cm-1 peak caused by heat effect, and weak Raman scattering peak. ⑥ UV-Vis absorption spectrum indicates that dyed opals are different from natural ones.

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于方,范桂珍,翁诗甫,等, 2014. 埃塞俄比亚染色欧泊的研究[J]. 岩石矿物学杂志, 33(s2):123~139.
YU Fang, FAN Gui-zhen, WENG Shi-fu, et al, 2014. A study of dyed opals from Ethiopia[J]. Acta Petrologica et Mineralogica, 33(s2): 123~139.

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  • 收稿日期:2014-08-20
  • 最后修改日期:2014-09-23
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  • 在线发布日期: 2014-12-02
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