利用红外3 036、3 058 cm-1吸收峰鉴定充填宝石需要注意的问题
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Some problems deserving attention in identifying the filled gems by the 3 036 and 3 058 cm-1 peaks of the FTIR spectra
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    摘要:

    翡翠经过漂白充填处理的结论性证据是红外光谱具有3 036、3 058 cm-1的吸收峰,对石英岩的充填处理该依据也是结论性的,随着市场新情况的出现,文献中对海蓝宝石、碧玺、石榴石、长石类宝石的充填处理也借助这两个与聚合物相关的峰诊断。但研究表明,有的宝石自身在3 100~3 000 cm-1范围内有吸收峰,还有的宝玉石在该范围内全吸收,会掩盖外来聚合物的吸收特征,此外,无机充填的宝石不具有3 100~3 000 cm-1范围内的特征吸收。因此,利用3 036、3 058 cm-1吸收峰判断宝石的充填需具体情况具体对待。

    Abstract:

    The most definitive testing method for the filled jadeite jade is infrared spectroscopy, because the presence of 3 036 and 3 058 cm-1 peaks is characteristic of polymer impregnation. The rule applies to the filled quartzite. In the past years there emerged many filled gems such as aquamarine, tourmaline, garnet and feldspar. The experts identified filled gems according to the two peaks due to polymer. However, the authors note that many minerals have the peaks or bands from 3 100 to 3 000 cm-1 of the FTIR absorption spectra and many gemstones absorb all the infrared light in that frequency range, so the peaks due to polymer might be covered up. The authors also warn that the gems impregnated with inorganic material would not present the absorbance from 3 100 to 3 000 cm-1. Therefore, whether the FTIR spectra show the absorbance peaks at 3 036 and 3 058 cm-1 or not, it is not the only, conclusive evidence that indicates whether the gems are filled or not. Different gems can't be compared absolutely with each other.

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李建军,李冬梅,山广祺,等, 2014. 利用红外3 036、3 058 cm-1吸收峰鉴定充填宝石需要注意的问题[J]. 岩石矿物学杂志, 33(S1):106~110.
LI Jian-jun, LI Dong-mei, SHAN Guang-qi, et al, 2014. Some problems deserving attention in identifying the filled gems by the 3 036 and 3 058 cm-1 peaks of the FTIR spectra[J]. Acta Petrologica et Mineralogica, 33(S1): 106~110.

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  • 收稿日期:2013-11-14
  • 最后修改日期:2013-12-23
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  • 在线发布日期: 2014-03-05
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