新疆和田喀拉喀什河青玉的组成及成因
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Composition and genesis of green nephrites from the Karakax River in Hetian, Xinjiang
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    摘要:

    和田玉仔料主要分布在玉龙喀什河和喀拉喀什河河床上,历史上这两条河流分别产出了高品质的白玉、青玉和墨玉。在以往的研究中,白玉的矿物学、谱学、考古学研究较多,墨玉也有过相关研究,而青玉研究非常少。本次研究采用电子探针(EMPA)对青玉样品进行测试分析。青玉样品含有少量的Cr和Ni元素(Cr2O3=0.00~0.06%,NiO=0.00~0.09%),与大理岩有关的软玉中Cr、Ni含量一致,而与蛇纹石有关的软玉(Cr2O3=0.07%~0.43%,NiO=0.08%~0.36%)相比明显不同。青玉中的副矿物有锆石、金红石、榍石、磷灰石,显示了岩浆来源的特征。根据岩相学研究,青玉中的主要矿物交代有Di→Dol,Tr→Di,Tr→Tr,Chl→Tr。次生矿床中青玉中透闪石的包裹体均一温度在200~400℃范围内,将在不同温度的成矿流体稳定同位素测试分析数据[δD=-39.4‰~-97.1‰,对应的δ18O=0.8‰~5.4‰,δ18OH2O=1.3‰~7.5‰(330℃),1.9‰~8.1‰(390℃),2.3‰~8.5‰(450℃)]与世界上其他类型的软玉矿床进行了对比,发现氢氧同位素特征与已有的大理岩型软玉一致,而与其他蛇纹石型软玉矿床差别较大。通过以上研究,认为这些青玉是通过岩浆岩与大理岩的接触交代形成的,成矿流体主要由岩浆热液和大气降水组成。

    Abstract:

    The Yurungkax River and Karakax River (White Jade and Black Jade) are two main placer nephrite sites located in Hetian, Xinjiang. They are well known historically for their valuable white, green and black nephrite, respectively, with a long history of use in the world. In this study, electron microprobe (EPMA) analysis was used to study green nephrite samples. The result shows that low Cr and Ni (Cr2O3 = 0.00 to 0.06% and NiO = 0.00 to 0.09%, respectively) are constant in these samples, consistent with the content of the marble-type nephrite but different from the content of serpentinite-related nephrite (Cr2O3 = 0.07% to 0.43% and NiO=0.08% to 0.36%). The accessory minerals in green nephrite include zircon, rutile, titanite and apatite which indicate the magmatic origin. According to petrographic study, several processes have been found in green nephrite: Di→Dol, Tr→Di, Tr→Tr, Chl→Tr. The homogenization temperatures for the inclusions in tremolite in green nephrite range from 200 to 400℃. Test data of the stable isotopes of the ore-forming fluid acquired at different temperatures show that the H and O isotopic values of green nephrite from the secondary deposit fall in the value range of existing marble-type nephrite, but are remarkably different from values of other serpentine-type nephrite deposits, as evidenced by a comparison with other types of nephrite deposits in the world. The results obtained by the authors show that green nephrite from secondary deposits was formed by contact metasomatism between magmatic rocks and marble, and that the ore-forming fluid was derived from magmatic hydrothermal fluid and precipitation.

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文茈燊,买托乎提&#;阿不都瓦衣提,鲁锋, 2014. 新疆和田喀拉喀什河青玉的组成及成因[J]. 岩石矿物学杂志, 33(S1):19~27.
WEN Zi-shen, Maituohuti Abuduwayiti, LU Feng, 2014. Composition and genesis of green nephrites from the Karakax River in Hetian, Xinjiang[J]. Acta Petrologica et Mineralogica, 33(S1): 19~27.

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  • 收稿日期:2013-11-26
  • 最后修改日期:2013-12-22
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  • 在线发布日期: 2014-03-05
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