藏西南札达白垩纪海绿石的形成机制及控制因素
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国家重点基础研究发展项目(2012CB822001);国家青年科学基金项目(41302033)


Mechanism and factors controlling the formation of glauconite:Evidence from the Cretaceous glauconite in Zanda, southwestern Tibet
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    摘要:

    西藏札达地区夏拉剖面海绿石砂岩之下的地层中含有少量处于不同演化阶段的海绿石质物质。为了更好的理解海绿石化过程、查明海绿石的形成机制和控制因素,本文利用岩相学和扫描电镜(SEM)以及电子探针微分析(EPMA)等技术,对其中处于不同演化阶段的海绿石进行了系统的矿物学研究。分析表明,海绿石呈微晶片状集合体形态,具明显的交代特征。海绿石化过程主要表现为交代碱性长石或岩屑中的富钾组分,这种交代反应为溶解-沉淀-重结晶机制控制的界面迁移反应。交代形成的海绿石继承了原矿物或岩屑颗粒的外形,表明其形成于很弱的水动力学条件。交代过程受沉积物供应速率、母源物质的溶解速率和反应界面附近的氧化还原条件控制。铁铝蛇纹石的大量存在表明当时的环境主要为一种还原环境,而海绿石则形成于局部的亚氧化(sub-oxic)环境中。砂岩中不同演化程度的海绿石都表现出富钾贫铁的特征,表明交代碱性长石(或钾长石)或岩屑中的富钾组分的海绿石化过程不同于前人提出的新生理论和两阶段模式。元素的富集是通过与交代作用同时进行的重结晶作用完成的,该过程不需要前人提及的后期单独的钾富集的过程,并区别于交代贫钾矿物的过程。

    Abstract:

    The Cretaceous rocks which contain glauconite at different stages of glauconitization lie under the glauconitic sandstone beds in the Xiala section in southwestern Tibet. To better understand the glauconitization process as well as the mechanism and factors that controlled the formation of glauconite, the authors studied the glauconite at different stages of glauconitization in the Cretaceous rocks of the Xiala section by means of petrographical microscope, Scanning Electron Microscope (SEM), and the Electron Probe Micro-Analyzer (EPMA). The results show that the glauconite generally occurs as granular aggregates composed of lamellae on the micron scale and has evident characteristics of replacement. The replacement of K in alkali feldspar dominated the interface migration reaction, which was controlled by a coupled dissolution-precipitation process, and a later stage of recrystallization. A long-term low-energy environment was necessary for the newly formed glauconite to retain the shapes of original mineral grains. Three factors were crucial at the initial stages of glauconitization: supply rates of sediment, dissolution rates of the substrate, and the redox condition near the reaction surface. The widespread occurrence of berthierine indicates that reducing condition was prevailed, and that glauconite only developed under local suboxic condition. The relatively high K2O content and low TFeO content of glauconite at different stages of glauconitization indicate that the process of glauconitization in the Xiala section could not be explained by the neoformation theory or the two-stage model postulated by previous researchers, because unlike the glauconitization of K-deficient minerals, the process in the Xiala section did not require a second stage of K enrichment.

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李响, 2014. 藏西南札达白垩纪海绿石的形成机制及控制因素[J]. 岩石矿物学杂志, 33(5):906~916.
LI Xiang, 2014. Mechanism and factors controlling the formation of glauconite:Evidence from the Cretaceous glauconite in Zanda, southwestern Tibet[J]. Acta Petrologica et Mineralogica, 33(5): 906~916.

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  • 收稿日期:2013-12-10
  • 最后修改日期:2014-07-11
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  • 在线发布日期: 2014-09-22
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