国内首次发现的束磷钙铀矿的矿物学特征
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国防科技工业局技术基础项目(J012011A004)


Mineralogy of phurcalite discovered for the first time in China
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    摘要:

    国内首次发现的粤北下庄铀矿田竹筒尖矿床产出的束磷钙铀矿,在空间上与微晶石英和变钙铀云母紧密共生。该矿物多为纤维状、束状和放射状集合体;亮黄色,玻璃光泽,透明;条痕为浅黄色,摩氏硬度约为3;其具有一组平行于{010}的完全解理及平行于{100}和{001}的两组解理,贝壳状断口呈油脂光泽;单偏光下,该矿物为淡黄色;正交偏光下,具有鲜艳的高级干涉色。光性特征为对称消光,二轴晶负光性,正延性。电子探针分析显示,矿物主要由U、P、Ca这3种元素组成,其平均含量分别为UO3 68.64%、P2O5 11.70%、CaO 9.21%和杂质0.28%,另有H2O 9.25%,总量99.26%。按O=16计算的经验化学式可写为(Ca2.02,K0.05,Mg0.012.08(UO2,TiO2,PbO)2.97O1.97(PO42.03·6.32 H2O。X射线粉晶衍射分析表明,该矿物属于正交晶系,空间群为Pbca,晶胞参数:a=1.742 3(5) nm,b=1.603 2(4) nm,c=1.359 9(2) nm;α=β=γ=90°,V=3.798 64 nm3 ;强衍射线有7.994 Å和4.003 Å等。矿物的红外吸收光谱强峰主要为3 427.10、1 622.05、1 062.62、973.26和890.91 cm-1等。上述特征与已知的束磷钙铀矿极其类似。

    Abstract:

    Phurcalite found in the Zhutongjian deposit of the Xiazhuang uranium ore field in northern Guangdong Province is associated with microcrystal quartz and meta-autunite in space. The mineral occurs as fibrous, fascicular and radiating aggregates and is bright yellow and transparent with vitreous luster. Its streaks are light yellow in color. The Mohs' hardness is about 3. Phurcalite has a perfect cleavage on {010}, good cleavages on {100} and {001}, and greasy luster conchoidal fracture. Under plainlight, phurcalite is light yellow, and it assumes high order bright interference color under crossed nicols. Phurcalite is a symmetrical extinction, biaxial negative, and positive elongation mineral. The chemical composition of phurcalite (EPMA, average of 15 points) is UO3 68.64%, P2O5 11.70%, CaO 9.21% and impurity 0.28%, with H2O 9.25%, totaling 99.26%. According to the data O=16, the empirical formula should be (Ca2.02, K0.05, Mg0.01)2.08(UO2, TiO2, PbO)2.97O1.97(PO4)2.03· 6.32 H2O. On the basis of the analyses of XRD, the system of phurcalite is orthorhombic, the space group is Pbca, and the unit cell parameters are a=1.742 3(5) nm, b=1.603 2(4) nm,c=1.359 9(2) nm; α=β=γ=90°, and V=3.798 64 nm3. Furthermore, the maxima (in cm-1) of the obtained infrared-absorption spectrum were observed: 3 427.10, 1 622.05,1 062.62, 973.26 and 890.91. These features are very similar to those of the known phurcalite.

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范光,于阿朋,葛祥坤,等, 2014. 国内首次发现的束磷钙铀矿的矿物学特征[J]. 岩石矿物学杂志, 33(1):95~101.
FAN Guang, YU A-peng, GE Xiang-kun, et al, 2014. Mineralogy of phurcalite discovered for the first time in China[J]. Acta Petrologica et Mineralogica, 33(1): 95~101.

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  • 收稿日期:2013-03-06
  • 最后修改日期:2013-08-05
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  • 在线发布日期: 2014-01-20
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