Schwertmannite矿物合成方法的优化和表征
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国家自然科学基金资助项目(41102096);国家国际科技合作专项资助项目(2012DFG71060)


Improvement of synthesizing methods and characterization of Schwertmannite
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    摘要:

    本文对Schwertmannite(斯沃特曼铁矿)矿物的两种非生物合成法——慢速合成法和快速合成法进行了全面的对比研究,并对合成样品的清洗方法进行了优化。慢速合成法和快速合成法在单纯合成Schwertmannite矿物的时间上基本一致。Schwertmannite矿物传统慢速合成方法中对合成样品的透析清洗过程耗时较长,但合成样品的矿物特征峰和红外光谱特性更好,形成的矿物颗粒较大;而Schwertmannite快速合成法中没有对合成样品的清洗步骤,并且合成样品的矿物特征峰强度较弱,合成的矿物颗粒较小。透析法比离心清洗法更适合对合成Schwertmannite样品的清洗,并且采用截留分子量为3 500的透析袋能够缩短透析时间20天,大大提高对合成样品的清洗效率。恒温(40℃)干燥会造成合成样品的严重聚集,而冷冻干燥法则能够大大降低合成样品在干燥过程中的聚集程度,通过研磨能够恢复干燥合成矿物原来的颜色和特征。

    Abstract:

    Two abiotic synthesis methods of Schwertmannite were studied through overall comparison, and cleaning methods of synthetic Schwertmannite were improved. Schwertmannite mineral synthesis time of the slow synthesis method and that of the rapid synthesis method are approximately the same. Mineral characteristic peaks and infrared spectrum characteristics of Schwertmannite by the slow synthesis method were more obvious than those of Schwertmannite's by rapid synthesis method. The mineral particle diameters of synthetic Schwertmannite by slow method were larger than synthetic Shcwertmannite by the rapid method. Dialysis cleaning process of synthetic Schwertmannite in traditional slow synthesis method is time consuming, but cleaning procedures of synthetic Schwertmannite are not included in the rapid synthesis method. Dialysis method is more suitable for cleaning synthetic Schwertmannie than the centrifugal method. Dialysis time can be reduced by 20 d through using dialysis bag with 3 500 molecular weight cutoff, and cleaning efficiency is raised greatly. Freeze-drying method can reduce greatly the aggregation degree of synthetic Schwertmannite than constant temperature (40℃) drying. Colors and characteristics of dried synthetic Schwertmannite can be recovered by grinding.

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引用本文

孙红福,赵峰华,吴山, 2013. Schwertmannite矿物合成方法的优化和表征[J]. 岩石矿物学杂志, 32(6):1006~1012.
SUN Hong-fu, ZHAO Feng-hua, WU Shan, 2013. Improvement of synthesizing methods and characterization of Schwertmannite[J]. Acta Petrologica et Mineralogica, 32(6): 1006~1012.

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  • 收稿日期:2013-03-16
  • 最后修改日期:2013-08-05
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  • 在线发布日期: 2013-11-19
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