大气降尘及人工粉尘在缬氨酸中的溶解特性研究
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国家自然科学基金资助项目(40072020,41130746)


The dissolution of natural dusts and artificial dusts in valine acid
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    摘要:

    针对自然降尘、工业区降尘及人工粉尘进行的物相、成分、表面形貌、元素含量及粒度分析表明,降尘均以石英、方解石、钠长石、绢云母为主要物相成分,SiO2、CaO含量较高,K2O、Na2O含量低。降尘粒度在0.3~5 μm内集中分布,小于2 μm的粉尘比例均超过85%。粉尘颗粒多为无规则的团块状,且颗粒表面粗糙。在模拟人体温度37℃条件下,对比研究了32 h内粉尘在缬氨酸水溶液中的溶出行为和电化学作用。不同性质的粉尘的pH值和电导率变化趋势不尽相同,大体上前4 h前各粉尘样品的pH值、电导率随时间增加上升较快,8 h后反应基本达到平衡。反应前后,溶液pH值改变较小,缬氨酸对粉尘溶解有较大缓冲作用。粉尘中元素K、Ca、Na、Mg的离子溶出总量为31~331 mg/L,其中Ca元素的溶出量最大为15~255 mg/L,其次为元素K、Mg、Na。重金属离子Fe、Zn、Mn、Pb、Ba、Cr、Ni、V的离子溶出总量为3.06~20.60 mg/L,Al、Si离子溶出总量为1.12~22.80 mg/L。粉尘中各元素主要在前8 h溶出较快,各粉尘在中性缬氨酸水溶液中的溶解程度由大到小为: 硅灰石>蛇纹石>海泡石;水泥厂降尘>自然降尘>电厂降尘。CaO含量高的水泥厂降尘和硅灰石人工粉尘溶解程度最大,表明其在中性缬氨酸环境中耐蚀性较差,表现出较低的生物持久性。SiO2含量高的电厂降尘和海泡石人工粉尘溶解程度最小,具有较强耐蚀能力和较高生物持久性。

    Abstract:

    This paper describes the characteristics of natural dusts, artificial dusts and industrial dusts in such aspects as mineral phases, chemical components, morphology and sizes. Quartz, calcite, albite and sericite constitute the main phases of natural dusts and industrial dusts with high SiO2, CaO and low K2O, Na2O in chemical composition. The fine particles are mainly in the range of 0.3 to 5 μm,of which the dusts of sizes less than 2 μm are over 85%. SEM observations show that the dusts are mainly irregular in shape, and the surface is rough. The dissolution and electrochemical action of dusts in valine acid liquor at the simulated human body temperature (37℃) in 32 hours were investigated. pH and electric conductivity values of these different dusts varied somewhat differently, and increased rapidly in the first 4 hours generally, and chemical reaction reached the equilibrium in 8 hours. Before and after the reaction, the pH values of the solution changed insignificantly; valine had larger buffer function on powder. The total amounts of dissolved ions of K, Ca, Na, Mg were in the range of 31 ~331 mg/L, with the amount of Ca dissolved ions being the highest, reaching 15 to 255 mg/L, followed by K, Mg, Na. The total amounts of dissolved ions of Fe, Zn, Mn, Pb, Ba, Cr, Ni, V were in the range of 3.06~20.60 mg/L and those of Al, Si were 1.12~22.8 mg/L. Each element was dissolved relatively rapidly in the first 8 hours. The relative solubility of dusts in valine acid was in order of wollastonite>serpentine>sepiolite; the cement plant industrial dusts>natural dusts>power plant industrial dusts. The wollastonite and power plant industrial dusts, which have high content of CaO, showed highest solubility, suggesting a poorer corrosion-resisting capability and lower bio-resistibility. Sepiolite and cement plant industrial dusts, which have high content of SiO2, showed lowest solubility, suggesting a higher corrosion-resisting capability and stronger bio-resistibility.

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张凌,董发勤,贺小春, 2013. 大气降尘及人工粉尘在缬氨酸中的溶解特性研究[J]. 岩石矿物学杂志, 32(6):849~856.
ZHANG Ling, DONG Fa-qin, HE Xiao-chun, 2013. The dissolution of natural dusts and artificial dusts in valine acid[J]. Acta Petrologica et Mineralogica, 32(6): 849~856.

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  • 收稿日期:2013-08-27
  • 最后修改日期:2013-10-12
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  • 在线发布日期: 2013-11-19
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