高压-超高压变质电气石研究的现状和进展
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国家自然科学基金资助项目(41121062;41272069;41090371)


Recent progress in HP-UHP metamorphic tourmaline research
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    摘要:

    本文总结了近年来有关高压-超高压变质电气石的研究成果,并在此基础上指出未来该领域的重点研究方向.电气石是一种分布广泛的矿物.实验证明其稳定存在的温度大于850℃,压力大于4 GPa.由于较慢的空间扩散作用、复杂的成分替代关系和较高的环境敏感度,电气石可以保存完好的生长环带.这有助于我们分析同位素演化、变质流体成分、岩石变质历史等.高压-超高压电气石结构化学研究表明电气石结构中的某些元素含量(如Al和F含量)和矿物的形成温度具有很好的相关性.根据不同的硼同位素来源,高压-超高压变质电气石的生长模型可以分为A型电气石、B型电气石和C型电气石.通过分析出露在全球各地的代表性高压-超高压变质电气石,其特征总体表现为: ① 多为镁电气石; ② X晶位具有很高的占位率(>0.8 pfu); ③ 化学结构中硼元素具有过量特征(3.2~3.3 pfu); ④ Ti、Mn、Li、Cl含量很低;⑤ 硼同位素成分的变化范围为: -16‰ <δ11B<+1‰.未来高压-超高压变质电气石的研究重点应该放在电气石晶体化学和变质p-t条件的关系、电气石-流体之间微量元素的分异作用以及含硼矿物组合的相平衡模拟等.

    Abstract:

    The recent research on HP-UHP metamorphic tourmaline is summarized in this paper. Tourmaline is a common mineral existent in sedimentary, igneous and metamorphic rocks. A variety of experiments demonstrate that this mineral can be stable in an exceptionally large p-t range, i.e. at p-t conditions >850℃ and >4 GPa. Owing to the low volume diffusion, the preservation of growth zones in tourmaline has become an effective key to investigating the boron evolution in rocks, the fluid-chemical history and the metamorphism of rocks. The research on the structure and chemistry of tourmaline reveals that components, such as Al and F are correlated with the formation temperature. According to different boron sources, the formation modes of HP-UHP tourmaline can be categorized into three types, i.e., Type A, Type B and Type C. Based on the analyses of typical HP-UHP tourmaline in the world, the authors sum up the general characteristics of this mineral: ① most HP-UHP tourmaline is dravite; ② the crystallographic X-site is highly occupied (>0.8 pfu); ③ excess B (3.2~3.3 pfu) is common; ④ Ti, Mn, Li and Cl have low abundances; and ⑤ the δ11B values range from -16‰ to +1‰. As for future work on HP-UHP tourmaline, we should highlight the relationships between crystal chemistry and p-t conditions during its formation, the trace-element partitioning between tourmaline and fluids, and the phase equilibrium modeling for B-bearing mineral assemblages.

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杨鑫,张立飞, 2013. 高压-超高压变质电气石研究的现状和进展[J]. 岩石矿物学杂志, 32(2):251~259.
YANG Xin, ZHANG Li-fei, 2013. Recent progress in HP-UHP metamorphic tourmaline research[J]. Acta Petrologica et Mineralogica, 32(2): 251~259.

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  • 收稿日期:2012-12-15
  • 最后修改日期:2013-01-17
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