新疆软玉、岫岩软玉的岩石矿物学对比研究
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中央级公益性科研院所基本科研业务费专项资助项目(K0921)


A petrological and mineralogical comparison between Xinjiang nephrite and Xiuyan nephrite
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    摘要:

    对新疆、岫岩软玉的典型品种进行了偏光显微镜、LA-ICP-MS、SEM等测试分析,证明两产地软玉的物理性质相似,但岫岩软玉光泽和透明度不如新疆软玉,其抛光的光洁度不如新疆软玉。黄白玉和绿玉在新疆软玉中基本上没有,而新疆软玉中的黄玉在岫岩软玉中基本上没有,这是两地软玉在颜色上的明显差别。微量元素均以青玉中的微量元素的总含量最高,Be、Ni、Cu元素对软玉中的绿色调有一定的影响。REE配分曲线显示了成矿流体的多来源和多期次叠加成矿的稀土元素特征。扫描电镜下观察,新疆软玉以毡状纤维交织变晶结构最为典型和常见;岫岩软玉以显微纤维结构和显微叶片状结构居多,颗粒较新疆软玉粗大,致密程度差,这也是其质地不如新疆软玉的重要原因。

    Abstract:

    Nephrite, widely distributed in nature, is one of the earliest natural jade resources developed and utilized in human history. The relatively well-known nephrite deposits in China include Hetian of Xinjiang, Xiuyan of Liaoning, Golmud of Qinghai and Hualien of Taiwan as well as some nephrite deposits discovered since the 1990's such as Xiaomeiling in Liyang of Jiangsu and Mianyang of Sichuan. Previous studies of nephrite were almost confined to the nephrite from a single producing area and were lacking in comparative work. There is also a lack of systematic research on the causes responsible for the differences in the texture of nephrites from different producing areas, which results in shoddy phenomena in the current market. Therefore, it is particularly important to seek for identifying symbols and quality appraising factors for nephrites from different producing areas. In this paper, the authors employed polarizing microscope, LA-ICP-MS and SEM analysis to study typical varieties of Xinjiang and Xiuyan nephrites. Test results show that physical properties of the nephrites from the two producing areas are similar to each other, but Xiuyan nephrite is not so good as Xinjiang nephrite in luster, transparency, and polished finish. There is almost no yellow-white jade and green jade in Xinjiang nephrite, and the yellow jade common seen in Xinjiang nephrite is on the whole not observed in Xiuyan nephrite, which accounts for the significant difference in color between the nephrites from the two areas. The content of the common coloring elements such as Be, V, Cr, Co, Ni and Cu in the two nephrite producing areas is not consistent, and there exists no corresponding relationship between the changing trend and the varieties. The total content of trace elements is the highest in green nephrite, and such elements as Be, Ni and Cu have a certain impact on the green color of nephrite. The ΣREE values of Xinjiang nephrite range from 1.4698×10-6 to 4.2217×10-6, the values of (La/Yb)N vary from 0.5663 to 10.8392 and δCe from 0.8115 to 0.9866; the ΣREE values of Xiuyan nephrite range from 5.1850×10-6 to 20.4230×10-6, the values of δCe vary from 0.8386 to 0.9885, and (La/Yb)N from 2.1071 to 5.6884. The nephrites from the two producing areas generally have low rare earth elements and clear differentiation of LREE and HREE, suggesting the enrichment of HREE. In addition, δEu are characterized by both positive and negative anomalies. The REE partition curve shows the REE features of multi-sources of ore-forming fluids and multi-period mineralization. The difference in the ore-forming source and the environment is the basic factor causing the different REE compositions of the nephrites from the two nephrite producing areas. Photomicrographs show that Xinjiang nephrite is mainly composed of fibrous, columnar, needlelike and flaky tremolite, and its impure minerals are composed of occasional limonite, ferric oxide and chlorite, illite and other clay minerals, whose content does not exceed 1%. It is colorless under polarization microscope and assumes middlepositive relief, with the relief gradually increasing with the increase of Fe content in samples. Its interference color is yellow to purple in Grade I. Xiuyan nephrite is similar to Xinjiang nephrite in mineral composition and structure, but it has larger particle sizes, poor compactness and larger gaps between the particles. The tremolite mainly has radiate fibrous and columnar shape through SEM observation, which seems to be the common character of the nephrites from the two producing areas, but Xinjiang nephrite has the most typical feltlike fiber woven blastic texture, with the particle sizes generally less than 3 μm and the lengths of columnar and fibrous particles generally less than 10 μm. Xiuyan nephrite commonly has micro-fiber and micro-leaf-shaped structure, and the tremolite grains assume leaf-shaped and fibrous distribution. The tremolite grains are thicker than those of Xinjiang nephrite, and the lengths are mostly in the range of 10~20 μm, with rather bad density. In addition, there are often uneven fractures or faults developed in the cleavage direction of tremolite in Xiuyan nephrite, which affects the quality of nephrite to a certain extent and seems to be an important factor causing the fact that its quality is not so good as that of Xinjiang nephrite.

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周振华,冯佳睿, 2010. 新疆软玉、岫岩软玉的岩石矿物学对比研究[J]. 岩石矿物学杂志, 29(3):331~340.
ZHOU Zhen_hua, FENG Jia_rui, 2010. A petrological and mineralogical comparison between Xinjiang nephrite and Xiuyan nephrite[J]. Acta Petrologica et Mineralogica, 29(3): 331~340.

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