利用钾长石粉体合成雪硅钙石的实验研究
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P579 TU551.37

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矿物材料国家专业实验室开放基金资助项目(04103)


The synthesis of tobermorite from potassium feldspar powder:An experimental study
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    摘要:

    以氧化钙为反应物料,在200~250℃的水热反应条件下分解钾长石。实验研究了在不同的Ca/(Si Al)摩尔比、水固比、反应温度和反应时间条件下,钾长石中K2O的溶出率和固相的物相变化。结果表明,液相中K2O的溶出率为40%~87%,固相反应产物为结晶良好雪硅钙石晶体。采用化学分析、XRD、SEM、DSC_TG和BET等方法对合成的雪硅钙石粉体进行了表征,结果表明,合成的雪硅钙石粉体是由长5~10μm、宽100~200nm、厚度为49~50nm的薄片纤维晶体交织成的直径为30~40μm的空心球形团聚体,耐火温度高于650℃,是制备硅酸钙保温材料的良好原料。

    Abstract:

    The dissolving rate of K2O from potassium feldspar and thesolid phase transformation were experimentally studied at 200~250℃ on hydrothe rmal-dissolving potassium feldspar, with CaO as the reactant and under the conditions of different Ca/(Al+Si) molar ratios, liquid/solid weight ratios, reaction temperatures and reaction periods. The experimental results indicate that the dissolving rate of K2O from potassium feldspar is 40%~80% and the solid product is well_crystallized fibrous tobermorite. Wet chemical analysis, XRD, SEM, DSC-TG and BET methods were used to characterize the synthesized tobermorite powers. The synthesized samples are hollow spherical agglomerates formed by fibroust obermorite crystals, which are 49~50 nm in thickness, 100~200 nm in width and 5~10 μm in length, suitable for making calcium silicate insulation materials.The heat insulating temperature of the synthesized tobermorite powder materials is as high as 650℃.

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张盼 马鸿文, 2005. 利用钾长石粉体合成雪硅钙石的实验研究[J]. 岩石矿物学杂志, 24(4):333~338.
ZHANG Pan, MA Hong_wen, 2005. The synthesis of tobermorite from potassium feldspar powder:An experimental study[J]. Acta Petrologica et Mineralogica, 24(4): 333~338.

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