天然锰钾矿吸附水溶液中Hg^2+的实验研究
DOI:
CSTR:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

P618.32;X703.1

基金项目:

国家自然科学基金资助项目(49972017)


The Sorption of Hg2+ from Aqueous Solution by Natural Cryptomelane
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    利用粉碎分级的天然锰钾矿去除水溶液中Hg^2 的实验研究表明:反应平衡时间约为20小时;pH值对其吸附率影响很大,在中性(氯化物在偏碱性)条件下吸附率较高;溶液中阳离子的存在会产生竞争吸附而降低对Hg^2 的吸附量,2价金属离子较1价金属离子对Hg^2 竞争干扰明显;溶液中Cl^-的存在能明显降低对Hg^2 的吸附量。对等温吸附曲线的回归分析得出在浓度为5~350mg/L段能很好地符合Langmuir单吸附位吸附曲线,并计算出在该实验条件下其最大理论吸附量为27.6mg/g。解吸实验结果表明,在无其他电解质参与的条件下解吸量较少,受多种电解质干扰时其解吸率不超过20%。

    Abstract:

    The sorption of Hg2+from aqueous solution was studied under variant conditions. Factors considered included diameters, pH values and different electrolytes .The final equilibrium was attained within 1~2 days.The investigation indicates that the gross adsorption quantity varies mainly with the pH values. In the solution that does not have other electrolytes or contains NaNO3or K2SO4, the gross adsorption quantity reaches the peak in neutral condition. As for the chlorates, the peak appears in the weakly alkaline condition. Comparing the effects of the ions, the authors conclude that the presence of Cl-decreases the gross quantity of the adsorption conspicuously, and the high value metal cations decrease the gross more effectively than the low value cations. The regression equation indicates that the adsorption of Hg2+between the concentration of 5 and 350 mg/L fits the single site langmuir sorption. The maximum adsorption quantity is 27.6 mg/g.

    参考文献
    相似文献
    引证文献
引用本文

郑德圣,鲁安怀,秦 善,等, 2001. 天然锰钾矿吸附水溶液中Hg^2+的实验研究[J]. 岩石矿物学杂志, 20(4):559~564.
ZHENG De-sheng, LU An-huai, QIN Shan, et al, 2001. The Sorption of Hg2+ from Aqueous Solution by Natural Cryptomelane[J]. Acta Petrologica et Mineralogica, 20(4): 559~564.

复制
相关视频

分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期:
  • 出版日期:
文章二维码