13X型沸石净化含铜废水的实验研究
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Experimental Research on the Application of 13X Zeolite to the Purification of Cu2+ -bearing Wastewater
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    摘要:

    本文研究了13X型沸石净化含Cu^2+废水的主要影响、吸附效果、解吸效果及净化机理。结果表明:碱性条件下的去除率略优于其他条件;吸附时间为10min,吸附基本达和;温度从20℃升高到50℃,去除率略有增另,当继续升高到65℃时,去除率下降。在达到国家污水综合排放标准(GB8978-88)前,每克沸石能处理浓度为30mg/L的废水1471.34ml,吸附量为43.40mg/g。用饱和NaCl溶液解吸后的沸石,其吸附率仍达到97.09%。废水净化机理为吸附作用和离子交换作用。实验证明,13X型沸石净化含Cu2+废水具有良好的工业化应用前景。

    Abstract:

    The primary influential factors, capacities of adsorption and desorption and mechanism for the purification of Cu2+_bearing wastewater by using 13X zeolite were experimentally investigated. The results showed that the optimal pH for the removal of Cu2+was 7~10 (alkalinity), the ratio of adsorption reached a plateau value when the adsorption time was 10 min. and increased with increasing temperature and reached a plateau value at 50℃. The volume of treated wastewater that contained 30 mg/L Cu2+by using 1 g zeolite was 1 471.34 ml, and the adsorption capacity was 43.40 mg/g. The concentration of wastewater after treatment attained 333 the national standard of drainage water. Spent 13X zeolite could be regenerated by sturated solution of NaCl without noticeable loss of capacity. Adsorption and ion exchange made up the major mechanism for the purification of wastewater. Experimental researches indicate that 13X zeolite is suitable for the purification of Cu2+_bearing wastewater.

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陶 红,马鸿文, 1999. 13X型沸石净化含铜废水的实验研究[J]. 岩石矿物学杂志, 18(4):329~334.
Tao Hong, Ma Hongwen, 1999. Experimental Research on the Application of 13X Zeolite to the Purification of Cu2+ -bearing Wastewater[J]. Acta Petrologica et Mineralogica, 18(4): 329~334.

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  • 最后修改日期:1999-03-23
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