辉锑锡铅矿表在的STM研究
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STM Study of Franckeite Surface
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    摘要:

    本文利用扫描隧道显微镜(STM)对辉锑锡铅矿(100)解理面的表面结构物征进行了研究,得到了清晰的原子级分辨率图像,并观察到辉锑锡铅结构中因两种基本构造层不匹则导致的调制波结构及超结构长周期现象,同时还观测研究了辉锑锡铅矿的表面微形貌特征。

    Abstract:

    Franckeite(Pb5Sn3;Sb2S14)is a kind of complex layered sulfide. The structure can be viewed as an alternate stacking of two false tetragonal symmetric t sheets(galena PbS sheets) and one false hexagonal symmetric h sheet(berndtite SnS2 sheet)along[100].Two kinds of sheets are packed in order of htthtt……along a axis. Because the unit cell of t sheets cannot correspond with the unit cell of h sheet and the missed matching between t sheets and h sheets the incommensurate-sinusoidal modulation waves have formed along c axis. Using type CSTMM一9000 Scanning Tunneling Microscopy, the authors observed the cleavage face {100}of franckeite and obtained excellent distinct atomic resolution STM image.The lattice parameters AB=0.366nm, AD=0.620nm indicated h sheet atomic arrangement of the cleavage face. The modulation sinusoidal waves of 4.7nm along caxis and a superstructure long period of 6. 98nm along b axis were also observed.Meanwhile the microtopographic character of franckeite was investigated with STM.

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马喆生,赵小平,施倪承, 1997. 辉锑锡铅矿表在的STM研究[J]. 岩石矿物学杂志, 16(3):237~243.
, 1997. STM Study of Franckeite Surface[J]. Acta Petrologica et Mineralogica, 16(3): 237~243.

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