中国宝石级钠柱石矿床的地质概况及其矿物学,宝石学特征
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Geology and Mineralogical-Gemmological Characteristics of Gem Marialite Deposit in China
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    摘要:

    中国已知的宝石级钠柱石矿床仅有一处,位于新扭阿克陶县苏巴什达坂北其依达 克附近。构造上属于中帕米尔摺皱带。该矿床沿构造破碎带呈脉状产出于元古界石榴黑云斜 长片麻岩中。构造破碎带的岩石具有明显的对称分带性:破碎带的中心为钠柱石矿体,向两侧 依次为榻石透辉石长英岩带、黑云母钠长岩带,并逐渐过渡为围岩。钠柱石矿的成因类型为沿 构造破碎带产出的热液交代脉型。钠柱石多与钠长石一同产出,呈四方柱状;浅紫一深紫色;透 明一半透明;折射率:No=1.541, Ne= 1.537;实测比重Dm=2.561g/cm3;硬度HM =5.5-6。利用化学分析和电子探针测定,其成分范围为Ma93.5-91.9 Me6.5-8.1,该成分相当罕见。X射 线粉晶衍射分析结果显示该矿床中的钠柱石为四方晶系;空间群I 4/ m;晶胞参数ao =12.0 (3)A,co=7.53(4)A, Z =2。经加工试验.该矿床中的钠柱石既可加工成刻面宝石,亦可加工 为带有明显猫眼效应的弧面宝石。原石残缺部分较少时.出成率可高达30%以上。

    Abstract:

    The sole gem marialite deposit in China is located at the western foot of Mount Muztagh,Akto County, Xinjiang, which is tectonically belongs to the Central Famirs fold belt. Gem marialite orebodies occur as veins along a structural shetter zone in the Proterozoic garnet-biotite-plagioclase gneiss. There is an obvious rock zonation from the middle to both sides of the structural shatter zone, generally from marialite orebody through diopside-felsite,biotite-albitite to the host Proterozoic rocks. This deposit was formed by hydrothermal metaso-matism。 Mainly in association with albite,marialite assumes tetragonal prism form,generally (0. 5-1 .2)×(1-2)cm in size with a few grains smaller than 0 .5 cm; transparent to translucent (attributed to the existence of gas-liquid inclusions) in hand specimens, and light to dard purple in color. Under mioroscope, it is colorless, optically uniaxial negative, with measured refractive indices No=1.541, Ne=1.537. Measured density 2.561 g/cm3;Moh’s hardness 5.5-6. X-ray powder diffraction data: tetragonal, I 4/ m,a0=12.0(3),c0= 7.53 (4)A, V=1084.3A3.wet chemical analysis and electron microprobe analysis give the composition of marialite as follows(in wt %):Na2O 11.37-11.60, A1203 18.94-19.98, SiO2 60.51-62.09, K201.20-1.88, Ca01.81-2.02, Cl 4.10-5.17, F<0.1, H20+ 0.27,suggesting that it is the Na end member of scapolite. The composition of scapolite has been traditionally expressed in term of Ma and Me ( Me=100×( Ca+Sr)/(Na+K+Ca+Sr)(Shaw, 1960;Ma= 100一Me),and the Ma and Me values of marialite from this deposit are Ma= 93.5-91.9 and Me=6.5-8.1. Almost all naturally occurring scapolites fall in the compositional range Ma 20-80 ( Orville, 1975 ).Pure marialite does not occur in nature and 80%Ma is the maximum attained ( Shaw, 1960 ).Ma of the marialite from this deposit is higher than 91, indicating that the mineral is a rare type in ature. Marialite from this deposit can be used as gem and can be cut into facet or cabochon,which has distinct chatoyancy. Research shows that the color of marialite is mainly caused by color center.

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曹亚文, 1996. 中国宝石级钠柱石矿床的地质概况及其矿物学,宝石学特征[J]. 岩石矿物学杂志, 15(2):158~169.
Cao Yawen, 1996. Geology and Mineralogical-Gemmological Characteristics of Gem Marialite Deposit in China[J]. Acta Petrologica et Mineralogica, 15(2): 158~169.

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