陕西略阳五花石的矿物学研究
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Mineralogical Study of Wuhuaite from Lueyang County, Shanxi Province
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    摘要:

    陕西略阳白水江所产五花石是一种石雕原料,其矿物成分以高岭石为主,并含有少量或极少量的褐铁矿、赤铁矿、重晶石、明矾石、三水铝右、炭质等。本文提供了高岭石的湿化学分析、X射线粉晶衍射、差热分析、红外吸收光谱、电子显微镜分析等多种方法测试的数据,证明它是属于有序度高、结晶良好的高岭石,可与苏州高岭石相比。由于成矿地质环境的特殊性,该五花石属硬质粘土,无天然塑性,质地坚硬、细腻,雕刻性能良好,是粘土类矿物所组成的别具风格的天然工艺石雕原料。

    Abstract:

    Wuhuaite occurring at Baishuijiang, Lueyang County, Shanxi Province, is a kind of material for stone carving.It has kaolinite as the major mineral compo- sition; and also contains small or negligible amounts of limonite,hematite, barite; alunite, gibbsite and cazbon materials. Chemical composition of kaolinite is SiO2 45.54 %,TiO2 0.05%,A1203 39.21%,Fe2O3 0.21%,Fe0 0.068%,MnO 0.016%,Ca0 0.22%,Mg0 1.33%,H2O+ 13.72%,K20 0.06% and Na2O 0.036%, totally 100.46%. Its crystallochemical formula is (Al3.985Fe(+3)0.013)3.988Si3.923O10(OH)8.Unit cell parameters: ao=5.142±0.006; bo=8.947±0.011; Co=7.363±0.009A; a=91º42´±11´; β=104º22'±11';γ=89º37±11'; V=328.007±0.503A.This paper alsb provides data of kaolinite obtained by various means such as X-ray powder diffraction, differential thermal analysis, infrared spectroscopic analysis and electron microprobe analysis, which prove it to be a kind of kaolinite with high order of degree and good crystalliuity. Formed in a specific geological environment, wuhuaite belongs to hard clay without natural plasticity and has hard, fine and smooth quality suitable for carving.Composed of clay minerals,it is a natural material for stone carving.

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张光荣,苏山立,苏昭冰, 1993. 陕西略阳五花石的矿物学研究[J]. 岩石矿物学杂志, 12(1):86~91.
Zhang Guangrong, Su Shanli, Su Zhaobing Shanxi Headquarters, et al, 1993. Mineralogical Study of Wuhuaite from Lueyang County, Shanxi Province[J]. Acta Petrologica et Mineralogica, 12(1): 86~91.

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