东秦岭地区钼矿床中辉钼矿的铼含量及多型特征
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Rhenium Content and Polytype Characteristics of Molybdenite from Molybdenum Deposits in East Qinling
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    摘要:

    辉钼矿是铼的最主要载体矿物。研究表明,东秦岭地区不同类型钼矿床中,辉钼矿的Re平均含量多为10—20ppm,其中仅黄龙铺碳酸岩脉型钼(铅)矿床的辉钼矿平均含Re高达152.5ppm。尽管辉钼矿中的铼含量有变化,但均呈类质同象取代钼而存在。同时,这些矿床辉钼矿的铼含量差异,主要取决于成矿热流体中原始铼含量。辉钼矿多型有2H型和2H+3R混合型。铼含量和成矿温度对辉钼矿多型没有影响,故辉钼矿多型对于钼矿床类型没有标型意义。

    Abstract:

    East Qinling is a major molybdenum metallogenic belt on the southern margin of the North China platform and contains Jinduicheng and Shijiawan porphyry type molybdenum deposits and Huanglongpu carbonate type molybdellilm (lead) deposit in Shanxi Province as well as Nannihu-Sandaozhuang and Shangfanggou porphyry-skarn type molybdenum (tungsten) and molybdenum(iron) deposits in Henan Province. Studies show that rhenium in molybdenite from the Huanglongpu molybdendm (lead) deposit has values of comprehensive utilization: the average Re content is 152.5 ppm, 14 times and 7 times higher than Re content of molybdenite from the porphyty type molybdenum deposit and from the porphyry-skarn type molybdenum (tungsten) deposit respectively (See Table 1). Nevertheless, as 187Re is unstable and frequently converts into 187Os, molybdenite as the major carrier of Re commonly contains different quantities of Os(See Table 1). Re and Os mainly occur in the form of isomorphism in molybdenite. As for polytypes, it is determined that molybdenite from different types of molybdenum in this region is exclusively of 2H type and 2H+3R type (See Fig. 4 and Table 2), with no relationship existent betWeen the polytype variety and the Re content or ore-forming temperature (See Table 2). It is therefore concluded that the difference in rhenium content of molybdenite from these molybdenum deposits depends mainly on geneses of these molybdenum deposits and initial rhenium concentrations of ore-forming hydrothermal fluids, whereas polytypes of molybdenite have no typomorphic significance for these types of molybdennm deposits.

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黄典豪, 1992. 东秦岭地区钼矿床中辉钼矿的铼含量及多型特征[J]. 岩石矿物学杂志, 11(1):74~83.
Huang Dianhao Institute of Mineral Deposits, Chinese Academy of Geological Sciences, Beiging , 1992. Rhenium Content and Polytype Characteristics of Molybdenite from Molybdenum Deposits in East Qinling[J]. Acta Petrologica et Mineralogica, 11(1): 74~83.

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