我国首次发现的锌—砷黝铜矿
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The First Discovery of Zn-Tennantite in China
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    摘要:

    锌-砷黝铜矿产于内蒙的某一铅锌矽卡岩矿床中,呈它形粒状集合体,粒径0.2-0.5mm,铅灰色,硬度HvHN=339-388kg/mm2。反射色呈灰蓝色微带绿色。均质性。其成分经电子探针分析(平均值)为:S 25.94,As 10.70,Cu 39.67,Zn 7.36,Sb 9.81,Bi 5.81,Ag 0.18,Fe 0.37(%),化学式为:(Cu10.02Age03)10.05(Zn1.81Fe0.11)1.82(As2.29Sb1.29Bi0.45)4.03S18。X射线分析:晶胞参数a=10.322A,粉末衍射强线是2.98A,1.82A,1.56A。

    Abstract:

    Zn-tennantite is a rare mineral discovered in a skarn lead-zinc deposit in Inner Mongolia. The associated minerals include chaleopyrite, sphalerite and galena. Zn-tennantite occurs as xenomorphic granular aggregates 0.2-0.5mm in diameter. It is lead grey in color, H_(VRN)=339-388 kg/mm2. Under microscope reflection color is greyish blue with a faint greenish tint.Electron microprobe analysis gives S 25.94, As 10.70, Cu 39.67, Zn 7.36, Sb 9.81, Bi 5.81,Ag 0.18 and Fe 0.37. The calculated chemical formula is (Cu(10.02) Ag(0.03))(10.05) (Zn(1.81)Fe(0.11))(1.92)(As(2.29)Sb(1.29)Bi(0.45))(4.03)S(13), quite similar to the ideal formula (Cu, Ag)(10) (Zn, Fe)2 (Sb, As)4S(13). The x-ray powder pattern of Zn-Tennantite is identical with that of tetrahedrite. Unit cell parameter a0=10.322(). The strongest lines in the powder diffraction pattern are 2.98(A), 1.82(A)and 1.56(A).It is smaller than tetrahedrite.

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雷蕴芬,林月英,张德全,等, 1991. 我国首次发现的锌—砷黝铜矿[J]. 岩石矿物学杂志, 10(2):176~180.
Lei Yunfen, Lin Yueying, Zhang Dequan, et al, 1991. The First Discovery of Zn-Tennantite in China[J]. Acta Petrologica et Mineralogica, 10(2): 176~180.

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