一种三八面体缘泥石/皂石1:1规则间层矿物(绿间皂石)的初步研究
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A Preliminary study of a Chlorite/Saponite(1:1) Regularly Interstratified Mineral
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    摘要:

    在湖北恩施利川地区的三叠系中统巴东组钙质砂质粘土岩及砂质泥质岩中,产出一 种褐灰色粘土矿物。通过X射线粉末衍射、红外、热分析、化学分析及电镜观察等测试研究,各 项实验数据证明该粘土矿物是三八面体绿泥石与三八面体皂石1:1规则间层矿物(绿间皂石)。自 然风干样和各种化学处理样的OOl衍射数据,都具育良好的整数倍关系。风干样001衍射的标准偏 差δ=0.1007,波动系数υc= 0.347。d060=1.531A, b0=9.19A,cosinβ=29.05A。并计算出了 该矿物的化学结构式。

    Abstract:

    A trioctahedral chlorite/saponite ( 1:1) regularly interstratified clay mineral (C/Sap) is found in Lichuan area, Ensbi county, Hubei province. Occurring in calcic-sandy clay rocks and sandy petite of Triassic Badong Group, it has irregutar scaled, shape, with G=2.75, H=1-2, and n=1.558-1.572.Detailed chemical analysis, X-ray diffraction, infrared absorption, thermal analysis and electron microscopy all indicate that this mineral is made up of altexinate trioctahedral chlorite and trioctahedral saponite layers, haviltg d 060=1.531A,b0=9.19A,and cosinβ=29.05A.A good integral sequence of 001 diffraction obtained for the air dry sample suggests a regular intetstratification, with δ=0.1007,υc== 0.347。 The chemical structural formula is(Mgo.26Cao.18 K0.09 Na0.03 H0.10)0.66(Mg6.32Al1.56Fe3+0.48Fe2+0.15)8.51(Si6.47Al1.56)8O20(OH)10nH2O. C/Sap of Lichuan resemble correrisite in IR spectra, Its wave numbers of abs- onion are 3670, 3556, 3415, 1630, 1080, 1002, 953, 898, 665, 650, 520, 460 and 445 cm-1.On DTA curve there are four endothermic effects(118℃,235℃,600℃,820℃) and one exothermic effects (852℃) The total weight loss of C/Sap is 15.9%,of which dehydroxylation weinht loss is 8.37%.

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张荣英, 1989. 一种三八面体缘泥石/皂石1:1规则间层矿物(绿间皂石)的初步研究[J]. 岩石矿物学杂志, 8(3):251~260.
, 1989. A Preliminary study of a Chlorite/Saponite(1:1) Regularly Interstratified Mineral[J]. Acta Petrologica et Mineralogica, 8(3): 251~260.

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