广西大厂长坡锡石硫化物矿床锡石晶胞参数的初步研究
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A Tentative Study on Unit Cell Parameter of Cassiterite from the Changpo Cassiterite Sulphide Deposit in Dachang, Guangxi
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    摘要:

    矿床为高中温热液型锡石硫化物矿床,通过研究知道随成矿温度由高到低,成矿阶段由锡石—石英经锡右硫化物到锡石—方解石,锡石晶胞的轴长,特别是c轴长和晶胞体积都有增大趋势。锡石中含有Fe等杂质元素,它们可以类质同像代替Sn,由于这些元素离子半径小,类质同像代替结果导致晶胞变小。而在高温条件下,元素类质同像代替较易进行,这就造成了高温阶段形成的锡石晶胞小,低温阶段形成的锡石晶胞大。

    Abstract:

    The ore deposit is a hypothermal-mesothermal cassiterite sulphide one.It has been revealed through the author's investigation that with the decreasein ore-forming temperature the mineralization stages varied from cassiterite-quartz through cassiterite-sulphides to cassiterite-calcite, and cassiterite sho-wed tendency of growth both in lengths of unit cell axes, especially axis C,and in unit cell dimensions. There exist such admixture elements as Fe in cassiterite which can subs-titute isomorphously for tin. As ionic radii of these elements are usually small,the isomorphism might cause unit cell to shrink. At high temperature, isomor-phous substitution of elements takes Place rather readily, and this probablyaccounts for small unit cell of cassiterite at high temperature and larger oneat low temperature.

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韩照信, 1987. 广西大厂长坡锡石硫化物矿床锡石晶胞参数的初步研究[J]. 岩石矿物学杂志, 6(4):368~371.
Han Zhaoxin Xian Institute of Geology, Xian, 1987. A Tentative Study on Unit Cell Parameter of Cassiterite from the Changpo Cassiterite Sulphide Deposit in Dachang, Guangxi[J]. Acta Petrologica et Mineralogica, 6(4): 368~371.

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