一种白云母/蒙皂石1:1规则间层矿物的初步研究
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A Preliminary Study on a Muscovite/Smectite (1:1) Regularly Interstratified Mineral
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    摘要:

    在湖北随县长岭地区变钠长辉绿岩与绢云母千枚岩接触带中,产出一种青灰色粘土矿物。经X射线衍射、红外、热分析、电镜观察及化学分析等方法研究,证明该矿物是一种二八面体白云母与二八面体蒙皂石的1:1规则间层粘土,(K2O含量达到4.97%)。风干样的00l衍射具有良好的整数倍关系,δ=0.059,VC=0.239,d(060)=1.503,a0=5.20,b0=9.02,c0sinβ=24.70并依据化学分析值计算出该矿物的化学结构式。

    Abstract:

    A sort of clay mineral bearing resemblance to rectorite is found in Chanling area, Suixian County, Hubei, Province. It occurs at the contact zone between metaholyokeite and albit-sericite phyllite as a product of alteration. It has irregular scaled shape, with G=2.79, H=2-3, Ng'=1.5494, and Np'=1.5436. The data obtained from such means as chemical analysis, X-ray diffraction,infrared absorption, thermal analysis and electron microscopy all indicate that this mineral is made up of alternate dioctahedral mica and dioctahedral smectite layers, having do60=1.503A,a0=5.20A,b0=9.02A and c0Sin β=24.70A。A good integral sequence of 001 diffraction obtained at room temperature suggests a regular interstratification, with δ=0.059 and VC=0. 239. Following are the formulae of dehydrated chemical structures: Mica-like layer: (K1.64Na0.41)2.05AL4[(Si6.08Al1.92)8O20]O2 smectite-like layer: (Ca0.53Mg0.16Na0.01K0.01H0.09)0.8(Al1.86Fe3+0.87Fe2+0.51Mg0.40Ti0.14)3.78[Si8O20]O2 The following experimental data of this mineral distinguish it from rectorite: 1. X.ray diffraction of the K-saturated sample shows d001=9.96A. 2. After being heated at 300℃, d001=9.83A. 3. Its water-saturated sample has d001=25.26A,showing only negligible eXPansion. 4. Its expanded layer has layer charge of 0.75, higher than that of recto- rite (0.3-0.6). It is thus tentatively considered that this mineral must be a muscovite/highly charged smectite (1:1) reg ularly,interstratified mineral.

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张荣英,吴方启, 1987. 一种白云母/蒙皂石1:1规则间层矿物的初步研究[J]. 岩石矿物学杂志, 6(2):163~170.
Zhang Yongying, Wu Fanqi, 1987. A Preliminary Study on a Muscovite/Smectite (1:1) Regularly Interstratified Mineral[J]. Acta Petrologica et Mineralogica, 6(2): 163~170.

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