STUDIES OF THE DETERMINATION OF RARE EARTH ELEMENTS AT ppb .LEVEL WITH ICP SPECTROMETRY
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This work concerns analyses performed by emission spectrometry employing ICP source for sample excitation. A domestic plasma generator was used and the porch was positioned horizontally to reduce background caused by intense plasma radiation and to increase the residence time of excited atoms in the source path, so that the limits of determination of 16 rare earth elements including scandium were nearly tenfold lower than that of conventional vertically positioned to3cch. The detection limits of different elements were in the range of O.OOx- O.Ox ug/ml. and would be in the range of O.OOOOx-O.OOx ug/ml. if desolvatiou system was used. The RSd are usually around 4%.
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袁玄晖,曾惠芳,伍新宇,等, 1983. ppb级稀土元素分量等离子光谱测定的研究[J]. 岩石矿物学杂志, 2(1):71~75. , 1983. STUDIES OF THE DETERMINATION OF RARE EARTH ELEMENTS AT ppb . LEVEL WITH ICP SPECTROMETRY[J]. Acta Petrologica et Mineralogica, 2(1): 71~75.