碰撞型斑岩铜矿中氯的来源及演化研究展望
CSTR:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

P595;P618.41

基金项目:

国家自然科学基金项目(41825005, 91955207, 92155305)


Prospects of the origin and evolution of chlorine in collisional porphyry copper deposits
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    斑岩铜矿作为一种岩浆热液型矿床,其形成过程与Cu在熔体与流体间的迁移密切相关。而大量研究表明Cl在这一过程中起到了至关重要的作用,因此岩浆中Cl含量的高低或直接决定了岩浆的成矿潜力。俯冲型斑岩铜矿成矿所需的Cl主要来自于俯冲大洋板片,而碰撞型斑岩铜矿形成时则缺乏洋片俯冲,因此其Cl的来源尚不确定。为了进一步推进对上述科学问题的探究,文章总结了常见含Cl岩浆矿物的富Cl特性及岩浆Cl逸度计的使用方法,并利用磷灰石估算了碰撞型斑岩铜矿成矿岩浆中的Cl含量;计算了新生下地壳角闪石与熔体间Cl和OH的交换系数,以此对冈底斯碰撞型斑岩铜Cl的来源进行讨论。研究显示: ① 成矿岩浆演化过程中结晶的磷灰石、角闪石和黑云母中的Cl含量可以指示岩浆或流体中的Cl逸度;② 碰撞型斑岩铜矿的成矿岩浆Cl含量明显低于俯冲型斑岩铜矿;③ 冈底斯出露的新生下地壳作为弧岩浆固结的产物,其中的角闪石可能继承了弧岩浆的高Cl含量特征;④ 印度陆壳俯冲过程中诱发地幔楔部分熔融所形成的超钾质岩浆可能含有较高的Cl含量。同时,幔源超钾质岩浆的加入将促进成矿岩浆中角闪石的大量结晶分异,有利于Cl在残余熔体中富集。

    Abstract:

    As a type of magmatic-hydrothermal deposit, porphyry copper deposits are closely related to the migration of Cu from melts to fluids. Many pieces of research have shown that chlorine plays a crucial role in this process, thereby the chlorine content directly determines the fertility of magma. The chlorine required for the mineralization of porphyry copper deposits in arc settings mainly comes from the subducting oceanic crust. But such an end-member is absent during the formation of a collisional porphyry copper deposit, the origin of chlorine in collisional settings is still uncertain. To further advance the research on the above scientific issues, this review summarizes the mineral characteristics of chlorine-containing magmatic minerals;estimates the chlorine content of fertile magma in collisional settings via apatite;calculates the exchange coefficient of amphibole in juvenile lower crust;discusses the chlorine source for porphyry copper deposit in collisional settings. The results show that: ① the Cl content in apatite, amphibole and biotite can be used to indicate the Cl content in melt or fluid;② Fertile magma from collisional settings have lower Cl content than its counterpart from arc settings, but the barren magma from arc environment have higher Cl content than its counterpart from collisional settings;③ The juvenile lower crust in Gangdese belt are the products of arc magma, and the consequent high Cl content can be inherited by the amphibole;④ The ultrapotassic magma formed by partial melting of mantle wedge during subduction of Indian continental crust may have high Cl content. And the Cl content of the residual melt will be further increased by the crystallization of amphibole, which is promoted by the addition of water-riched ultrapotassic magma.

    参考文献
    相似文献
    引证文献
引用本文

周怿惟,杨志明,周利敏, 2023. 碰撞型斑岩铜矿中氯的来源及演化研究展望[J]. 岩石矿物学杂志, 42(3):417~441.
ZHOU Yi-wei, YANG Zhi-ming, ZHOU Li-min, 2023. Prospects of the origin and evolution of chlorine in collisional porphyry copper deposits[J]. Acta Petrologica et Mineralogica, 42(3): 417~441.

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2022-11-24
  • 最后修改日期:2023-04-03
  • 录用日期:
  • 在线发布日期: 2023-05-20
  • 出版日期: 2023-05-25
文章二维码