含霞石翡翠的成因研究
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The petrogenesis of nepheline jade
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    摘要:

    本文针对鲜有报道的含霞石翡翠,选择了若干具有代表性的样品进行了详细的岩相学、矿物化学、拉曼光谱和X射线粉晶衍射等方面的研究,并对其成因进行了深入探讨。本研究中的样品属于翡翠中的“飘蓝花”品种,为柱粒状结构,主要由硬玉、霞石、角闪石和少量的钡铝硅酸盐等组成。硬玉可分为两个世代,早期硬玉呈自形,发育规则的环带结构,反映了成岩流体的反复补给过程。早期自形的硬玉颗粒部分被后期细粒化的硬玉±角闪石取代,反映了后期流体事件的改造作用。根据产出和成分特征可将霞石分为两种:贫钾霞石和富钾霞石,其中贫钾霞石多沿自形的硬玉颗粒边界分布,而富钾霞石充填在自形的硬玉颗粒之间。根据结构特征可以推测,含霞石翡翠主要是从成岩流体中直接结晶形成的。矿物组成及其成分特征表明该成岩流体主要富集Na、Al、Si、K、Ba以及少量的Ca、Fe、Mg等元素,微量元素则相对富集LREE、HFSE和Sr等元素。结合样品中的矿物相关系和前人的研究结果,含霞石翡翠中硬玉的结晶压力和温度范围分别被限制在0.6~1.4GPa和300~450℃之间,其中霞石代表着母岩减压后流体活动的产物。

    Abstract:

    In this paper, the authors conducted detailed researches on the rarely-reported nepheline jades in the aspects of petrography, mineral chemistry, Raman spectroscopy and X-ray powder diffraction, with a discussion on their petrogenesis. The jades in this study belong to the "floating blue flower" variety and are mainly composed of jadeite, nepheline and hornblende with minor Ba-aluminosilicates, assuming a tubular texture. Jadeites in these samples have two generations: the earlier ones are euhedral and show regular oscillatory zoning, indicating iterative replenishment of diagenetic fluids during the growth of jadeites; the earlier jadeites are partly replaced by later fine-grained jadeite ± amphibole, indicating the alteration caused by later fluids. On the basis of its modes of occurrence and compositions, nepheline can be divided into two types, i.e., K-poor nepheline and K-rich nepheline, in which the former occurs along the grain boundaries of the euhedral jadeites whereas the latter fills in the space between the euhedral jadeites. The textural features indicate that the nepheline jades were directly precipitated from fluids. The mineral assemblage and compositions suggest that the fluids were rich in Na, Al, Si, K, Ba with small amounts of such major elements as Ca, Fe and Mg, while the trace elements are characterized by enrichment of LREE, HFSE, Sr, etc. Combining the phase relations between the minerals in the samples with the results from previous studies, the authors hold that the crystallization p-t conditions for the jadeites should be confined to 6~14 GPa and 300~450℃. The nepheline in the jades represents the precipitation product of fluids after decompression.

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韩辰婧,王雅玫, 2014. 含霞石翡翠的成因研究[J]. 岩石矿物学杂志, 33(3):581~590.
HAN Chen-jing, WANG Ya-mei, 2014. The petrogenesis of nepheline jade[J]. Acta Petrologica et Mineralogica, 33(3): 581~590.

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  • 收稿日期:2013-10-22
  • 最后修改日期:2014-03-24
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  • 在线发布日期: 2014-05-29
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