热液矿床中萤石的稀土元素地球化学及其地质意义
DOI:
CSTR:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

中国科学院矿床地球化学国家重点实验室“十二五”项目群(SKLODG-ZY125-02);国家自然科学基金项目(41102055,41102053);山东黄金集团科研项目


Rare earth elements geochemistry of fluorite in hydrothermal deposits and its geological significance
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    萤石是许多热液矿床中重要的脉石矿物,其稀土元素含量及相关参数(如∑REE、LREE/HREE、Eu/Eu*、Ce/Ce*、Y/La、Tb/Ca-Tb/La图解等),能为揭示成矿流体性质、来源与演化,建立成矿模式,评价区域成矿潜力等提供重要信息。然而,随着微区分析技术的日趋成熟,原位实测数据显示,萤石中微量元素(包括稀土元素)的分配在显微尺度上可能具有不均一性,致使依据萤石溶液法获得的稀土元素含量所反映地质信息的可靠性受到质疑。因此,在应用萤石稀土元素地球化学探讨相关地质问题前,有必要加强萤石微观结构的观察和配套的流体包裹体以及相关同位素组成分析。本文在综述萤石稀土元素地球化学研究基础上,初步探讨了影响萤石稀土元素不均一分配的主要机制,以期为萤石稀土元素在热液矿床成因研究中的应用提供借鉴。

    Abstract:

    Rare earth elements are important tracers in probing the source of ore-forming fluid and discussing the process of hydrothermal mineralization. As a calcic mineral, fluorite is one of the most important gangue or ore minerals present under various temperature conditions in many hydrothermal deposits. REE3+ tends to enter the crystal lattice of fluorite, attributed to the similarity of ion radius and crystallochemistry between Ca2+ and REE3+. In addition, fluorite is a significant medium in the study of hydrothermal deposits. The rare earth elements in the fluorite are susceptible to the source of fluid, the condition of leaching rocks during migration and evolution, the chemical composition, redox conditions and the form of transportation in the fluid. Besides, the rare earth elements content and relative geochemical parameters of fluorite, such as ∑REE, LREE/HREE ratio, Eu, Ce, Y anomaly, Ta/Ca-Ta/La diagram, Y/La ratio and mode of occurrence of REE2+ (except Eu2+), and other rare earth element geochemical characteristics could provide important geological information concerning the source, physico-chemical property and the evolutionary process of the hydrothermal fluid, and they could also provide message crucial for developing metallogenic model and making inferences about the metallogenic potential of the regions in which they occur. However, with the development of the microanalysis technology, the in-situ trace element analysis of fluorite implies that it is probable that the distribution of trace elements (including rare earth elements) of fluorite is inhomogeneous at the micro level, which might result in the questioning of applying rare earth elements, obtained by the solution method, of fluorite in the hydrothermal deposit to probing the geological information. Therefore, it is necessary to pay more attention to the comprehensive study of fluorite in microstructure, fluid inclusion and isotopic analysis before applying the rare earth element geochemistry to probing relevant geological issues. Thus, in this paper, the authors summarized recent status and progress in rare earth elements geochemistry of fluorite, and discussed the dominant mechanisms leading to inhomogeneity in rare earth elements distribution in fluorite tentatively, looking forward to providing more valuable reference for rational understanding of rare earth element geochemistry of fluorite in the hydrothermal deposit.

    参考文献
    相似文献
    引证文献
引用本文

孙海瑞,黄智龙,周家喜,等, 2014. 热液矿床中萤石的稀土元素地球化学及其地质意义[J]. 岩石矿物学杂志, 33(1):185~193.
SUN Hai-rui, HUANG Zhi-long, ZHOU Jia-xi, et al, 2014. Rare earth elements geochemistry of fluorite in hydrothermal deposits and its geological significance[J]. Acta Petrologica et Mineralogica, 33(1): 185~193.

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2013-01-13
  • 最后修改日期:2013-07-18
  • 录用日期:
  • 在线发布日期: 2014-01-20
  • 出版日期:
文章二维码