南秦岭安康地区热液脉型高纯石英原料发育特征及质量影响因素分析
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中国建筑材料工业地质勘查中心陕西总队

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P574.2

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Analysis of raw material characteristics and quality influencing factors of hydrothermal vein type high-purity quartz in Ankang area of the South Qinling Mountain
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1.Shaanxi Branch of China National Geological Explorational Center of Building Materials Industry,Xi'2.'3.an

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    摘要:

    南秦岭安康地区志留系梅子垭组千枚岩中赋存丰富的脉石英矿产资源,但作为高纯石英原料研究程度低,尤其是对影响石英提纯的痕量杂质含量及赋存状态缺乏系统认识,很大程度制约了本区高纯石英原料的质量评价和进一步的找矿突破。本文在厘定脉石英地质发育特征的基础上,对3个地区产出的3件脉状石英样品(AK200、AK201、AK202),开展了样品杂质元素检测,对样品矿物学特征、杂质赋存形式和可提纯性能进行了研究,在此基础上进行了提纯试验,结果显示:AK200、AK201、AK202三件样品提纯后SiO2含量分别为99.99311%、99.99766%、99.99858%,均达到高纯石英产品质量要求,其中AK202样品提纯后达到4N8级。研究表明,提纯后Al、Ti、Na、K为主要杂质元素,Al多以杂质矿物、晶格杂质两种方式存在;Ti多以晶格杂质的方式存在;Na、K多以流体包裹体的方式存在;杂质矿物、流体包裹体、晶格杂质对该区脉石英质量均产生不同程度影响,其中流体包裹体为主要影响因素、晶格杂质次之、杂质矿物影响最小。这一结论对于评价该区的脉石英矿产资源质量,明确今后找矿目标体特征具有重要参考意义。

    Abstract:

    There are abundant vein quartz mineral resources in the Silurian Meiziya formation phyllite in the Ankang area of the South Qinling Mountains, but the research degree as a high-purity quartz raw material is low, especially the content and occurrence state of trace impurities that affect the purification of quartz are lacking systematically to a large extent, it has restricted the quality evaluation of high-purity quartz raw materials in this area and further breakthroughs in prospecting. In this paper, on the basis of determining the geological development characteristics of vein quartz, three vein quartz samples (AK200, AK201, AK202) produced in three regions were tested for impurity elements in the samples. The purification performance of AK200, AK201 and AK202 was studied, and the purification test was carried out. The results showed that the SiO2 content of the three samples after purification was 99.99311%, 99.99766% and 99.99858%, respectively, all of which reached the quality of high-purity quartz products. requirements, in which the AK202 sample reaches 4N8 level after purification. The research shows that after purification, Al, Ti, Na and K are the main impurity elements, and Al mostly exists in the form of impurity minerals and lattice impurities; Ti mostly exists in the form of lattice impurities; Na and K mostly exist in the form of fluid inclusions. Impurity minerals, fluid inclusions, and lattice impurities all have varying degrees of influence on the quality of the vein quartz, among which fluid inclusions are the main influencing factor, lattice impurities are the second, and impurity minerals have the least impact. This conclusion has important reference significance for evaluating the quality of vein quartz mineral resources in this area and clarifying the characteristics of future prospecting targets.

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  • 收稿日期:2022-06-25
  • 最后修改日期:2022-09-06
  • 录用日期:2022-11-04
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